The Leaving Home/Galvanize live track is good... but I think that the Swoon/Star Guitar track is perfection. Everyone I have introduced Chemical Brothers to goes crazy for that live track.
Also the remixes are alright but I think Chemical Brothers have enough amazing tracks of their own that can make up a beginner's compilation.
Some other tracks that have really gotten attention from people that I've introduced the Chems to are:
Saturate
Under The Influence
Out of Control
Another World
Believe
Hey Boy Hey Girl


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